If my opponent used Gardevoir EX's "Shining Wind" attack to gain "no Weakness" and I play Pokemon Ranger when it is my turn, does their Gardevoir EX have a Weakness again?

Yes. The ruling about effects on Weakness and Resistance not being ignored has to do with damage calculations [see "General Gameplay -> Weakness and Resistance" section for reference], not about whether a Pokemon HAS Weakness or Resistance. Pokemon Ranger removes attack effects, including this one; so yes, Gardevoir EX would have Weakness again after using Pokemon Ranger.

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