If my opponent used Scyther's "Afterimage Strike" last turn, and on my turn I use an attack like "Double Slap" to flip two coins and do 30x the number of heads, if the opponent gets heads on "Afterimage Strike" to prevent the damage, can I use Victini's "Victory Star" Ability to reflip my coins for "Double Slap" and start the process all over again?
No, you cannot. Victory Star must be invoked prior to determining the amount of damage being done, which in turn is prior to the opponent performing the flip for Afterimage Strike.
Source: TPCi Rules Team (2012-01-12)

Relevant cards

Note: All applicable cards may not be listed below.
BW11_23
BW3_14
BW3_98
BWP_BW32
BWP_BW32
SM2_10