Can I attach a Shield Energy to Lucario with the "Dual Armor" Ability?
It depends on when the Shield Energy is being attached. If Lucario already has a Metal Energy attached to it Dual Armor makes Lucario both Fighting & Metal types, so you CAN attach Shield Energy at that point. However, if Lucario does not already have a Metal Energy attached or if its Dual Armor ability has been shut off, then you CANNOT attach a Shield Energy to Lucario.
Source: TPCi Rules Team (2016-02-25)

Relevant cards

Note: All applicable cards may not be listed below.
BW8_78
XY5_143